出版物: 2019 年 10 月 16 日 最近更新時間: 2025 年 3 月 10 日

新的技术性能将 TPE 和弹性体的优点集于一身


凯柏胶宝®将在 K 2019 展会上推出针对热塑性弹性体混合物的灵活材料开发平台

为缩小热塑性弹性体与传统弹性体化合物之间的性能差距,凯柏胶宝®专为热塑性弹性体混合物(TEH)推出了新的先进技术平台。TEH 化合物是专为客户特定应用而量身定制的产品。此款化合物与选定的弹性体相结合,既具有与弹性体相同的特征,又保持了 TPE 优良的可加工性。公司将在杜塞尔多夫举办的 K 2019 贸易展览会期间(6 号展厅,C-58-05 和 E22 展位)详细介绍这项创新技术。

热塑性弹性体制造商一直在努力寻找途径来延续经典弹性体的性能。尽管我们在热塑性共聚酯弹性体(TPC)和热塑性聚酰胺弹性体(TPA)领域已取得了一些成功,但以前始终无法找到能与弹性体或橡胶性能相匹配的“通用超级 TPE”。这主要是由于该领域中的典型应用多种多样。

“为了缩小已有 TPE 和弹性体之间的性能差距,尤其是耐热性方面,我们正在采取一种严密关注应用和客户方法,”凯柏胶宝®欧洲、中东和非洲(EMEA)业务开发主管 Dirk Butschkau 表示。“例如,我们根据每种化合物的特定相容性和所需应用温度、耐化学性和力学性能的适用性,来选择弹性体和热塑性塑料的比例。”

努力的结果,就是我们一款与弹性体成分完全交联的“定制工艺”TEH 化合物。与传统弹性体混合物相比,它可以让注射模型成形机像以往一样经济地加工技术热塑性塑料。不再需要大多数弹性体通常必不可少的精加工,即便是含 PP、PBT 或 PA 的复杂精细的双组份应用也可以无需粘合剂。

新技术平台可提供邵氏 A 硬度范围为 55 至 80 的先进 TPE 材料,由于采用两种材料——弹性体和热塑性塑料构成,因此具有出色的优化性能。除了优良的力学性能外,这些材料还具有高达 150 °C 的连续工作温度,以及对油脂、润滑剂和燃料的出色耐化学性。此外,由于从 TEH 生产成型品时材料不交联,它们还具有完全可回收性。

与普通弹性体相比,TEH 化合物的热塑性可加工性可在同等壁厚和射胶下将成型时间缩短多达 80%。这意味着它们不仅可提供极具成本效益的替代方案,还可适用于各种可能的新应用。工艺和特性专门针对发动机盖、油槽、燃料加注盖和油盖的部件,以及冷却和/或温度控制单元。其他适用的例子有齿轮箱、发动机和泵中的吸音和减震部件,还有连接器、螺纹电缆密封套和紧固件。初期成功用例包括在 2 升柴油发动机的润滑回路中使用、与发动机油长期接触并且在用冷发动机驱动期间暴露于大量的柴油和油气之中。

经过长期的开发和各种基础研究调查,凯柏胶宝®看到了进一步开拓这项刚刚引入市场的新技术的巨大潜力。“我们目前正在测试使用丁基橡胶来改善阻隔性能,正在想办法来实现低于邵氏 A 50 硬度的更软的 TEH 等级,”Butschkau补充道:“热塑性塑料的选择很广泛,包括 PE、PBZ、PET、TPO 和 TPU 等塑料,它们都会对材料特性产生不同的影响。”

K 2019 展会期间,凯柏胶宝®将盛邀参观者结识凯柏胶宝®的材料和市场专家,参观 6 号展厅 E22 展位,与技术专家进行技术讨论,并亲眼见证新 TEH 技术所带来的优势和机遇。

表:与橡胶和标准 TPE 化合物(TPS/TPV)相比的热塑性弹性体杂化物的性能

(图片来源:© 2019 凯柏胶宝®版权所有)

A new performance class combines the advantages of TPEs and elastomers


KRAIBURG TPE will be presenting a flexible material development platform for thermoplastic elastomer hybrids at K 2019

KRAIBURG TPE has introduced an advanced new technology platform for thermoplastic elastomer hybrids (TEHs), to close the performance gap between thermoplastic elastomers and conventional elastomer compounds. The TEH compounds are tailor-made to fit customers’ specific applications. Combined with selected elastomers, the compounds provide the same features as elastomers while maintaining the favorable workability of TPEs. The company will be presenting this innovative technology in detail during the K 2019 trade fair held in Düsseldorf (Hall 6, Booths C-58-04 and E22)

TPE manufacturers have been trying all along to find ways of catching up with the performance of classic elastomers in their products. Although there have been a few successes with thermoplastic copolyester elastomers (TPCs) and thermoplastic polyamide elastomers (TPAs), it has not previously been possible to find a “universal super-TPE” that could match the properties of elastomers or rubbers. This is mainly due to the wide variety of typical applications in the field.

“To close the performance gap between established TPEs and elastomers, particularly in relation to thermal resistance, we are therefore taking an approach that focuses rigorously on applications and customers,” explains Dirk Butschkau, Head of Business Development EMEA at KRAIBURG TPE. “For example, we select the proportions of elastomers and thermoplastics in each compound on the basis of their specific compatibility and suitability for the required application temperature, chemical resistance and mechanical performance.”

The result is a “custom-engineered” TEH compound with a completely crosslinked elastomer component – which in contrast to conventional elastomer mixtures can be processed just as economically for injection molders of technical thermoplastics. The finishing that is usually necessary with most elastomers is not necessary and even sophisticated two-component applications with PP, PBT or PA can be implemented without bonding agents.

The new technology platform provides advanced TPE materials with a hardness range of 55 to 80 Shore A, with significantly improved performance based on different combinations of elastomers and thermoplastics. Along with excellent mechanical properties, the materials provide continuous operating temperatures up to 150 °C and outstanding chemical resistance to oils, greases, lubricants and fuels. In addition, they remain completely recyclable, as the material is not crosslinked during the production of moldings from TEH.

The thermoplastic workability of TEH compounds may reduce the cycle time at comparable wall thicknesses by up to 80% in comparison with elastomers. This means they provide not only an extremely cost-effective alternative but also a wide range of possible new applications. The processing and characteristics profile are aimed particularly at parts of engine covers, oil sumps, fuel filler caps and oil caps, as well as cooling and/or temperature control units. Additional examples are noise-absorbent and vibration-absorbent components in gearboxes, engines and pumps, and also includes connectors, screwed cable glands and fasteners. The initial successes include an application that is used in the lubrication circuit of a 2-liter diesel engine, in permanent contact with the engine oil and exposed to considerable amounts of diesel and blow-by gases during driving with a cold engine.

Following an extensive development phase and various basic research investigations, KRAIBURG TPE sees tremendous potential for further expansion of this new technology, which has only recently been introduced in the market. “We are currently testing the use of butyl rubbers to improve barrier properties and we’re following various approaches to achieve softer TEH ratings below 50 Shore A,” says Butschkau, adding: “The wide choice of thermoplastics also includes plastics such as PE, PBZ, PET, TPO and TPU to influence certain material properties in specific ways.”

Visitors to K 2019 are invited to join KRAIBURG TPE’s materials and market experts for a technical discussion at the think tank at Booth E22 in Hall 6 and see for themselves the advantages and opportunities that the new TEH technology offers.

凯柏胶宝® - 快览
 

  • 总部和生产基地:瓦尔德克赖堡/德国
  • 区域总部和生产基地:吉隆坡/马来西亚,亚特兰大/美国
  • 产品:热塑性弹性体化合物
  • 品牌:热塑宝、科柔宝®、高温宝和尼塑宝®
  • 市场:欧洲、美洲、亚太地区
  • 员工:660

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